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An Efficient Algorithm for Automating Classification of Chemical Reactions into Classes in Ugi’s Reaction Scheme

An Efficient Algorithm for Automating Classification of Chemical Reactions into Classes in Ugi’s Reaction Scheme
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Author(s): Sanjay Ram (Bengal Engineering and Science University, Shibpur, India)and Somnath Pal (Bengal Engineering and Science University, Shibpur, India)
Copyright: 2013
Pages: 12
Source title: Methodologies and Applications for Chemoinformatics and Chemical Engineering
Source Author(s)/Editor(s): A. K. Haghi (University of Guilan, Iran)
DOI: 10.4018/978-1-4666-4010-8.ch018

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Abstract

There are two approaches for classification of chemical reactions: Model-Driven and Data-Driven. In this paper, the authors develop an efficient algorithm based on a model-driven approach developed by Ugi and co-workers for classification of chemical reactions. The authors’ algorithm takes reaction matrix of a chemical reaction as input and generates its appropriate class as output. Reaction matrices being symmetric, matrix implementation of Ugi’s scheme using upper/lower tri-angular matrix is of O(n2) in terms of space complexity. Time complexity of similar matrix implementation is O(n4), both in worst case as well as in average case. The proposed algorithm uses two fixed size look-up tables in a novel way and requires constant space complexity. Time complexity both in worst and average cases of the algorithm is linear.

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